Organic chemistry ii lab school of science and technology experiment j aldol condensations to produce trans-p-anisalacetophenone, [959-33-1. Section 183 synthesis of trans-p-anisalacetophenone name (print): date: why is the condensation (dehydrated) product rather than the aldol addition (hydrated. The aldol condensation is a reaction that is named based on the type of product formed when two aldehydes (or ketones), in the presence of dilute base, yields a molecule having both alcohol and aldehyde functional groups.
Aldol condensation: preparation of trans-p-anisalacetophenone (preparative) (procedure, quest) (product analysis: ir, mp, % yield) chemiluminescence: synthesis of luminol. Please provide the mechanism for reacting p-anisaldehyde with acetophenone to get trans-p-anisalacetophenone and if you wouldn't mind give a brief description of how the reaction occurs due to crossed aldol condensation. Aldol condensation-preparation of trans p-anisalacetophenone (pp619- 620) week 13, mon 4/tues 5/thus 7 may concerted reactions (ch 20, pp 1046-1072) + quiz 10.
aldol in this preparative lab, an aldol (trans-p-anisalacetophenone) was produced from the reaction between p-anisaldehyde and acetophenone with the presence sodium hydroxide the reaction also showed the importance of an enolate and the role it played in the mechanism. Aldol condensation you are to prepare anisalacetophenone (aka 4-methoxychalcone) via an aldol condensation according to the directions on page 323 of your lab text you will recrystallize the crude product from 95% ethanol. Experiment 13 aldol condensations 36 weekly reports archive of weekly reports from rv polarstern c nmr lab report - download as pdf file (pdf), text file (txt) or read online. Created date: 4/7/2009 11:11:52 am. Keywords: aldol addition, aldol condensation, dianisalacetone, recrystallization, unsaturation aldol condensation is the elimination of the hydroxyl group to produce an unsaturated bond aldol addition reactions happen when aldehyde is treated with a base.
Aldol condensation preparation of trans p-anisalacetophenone kinetic/thermodynamic control of a reaction (pp 440-443) make-up [ written assignment , nmr product analysis reports due this day. Aldol condensation in some cases, the adducts obtained from the aldol addition can easily be converted (in situ) to α,β-unsaturated carbonyl compounds, either thermally or under acidic or basic catalysis. Syllabus for chemistry 2182 (fall, 2007) organic chemistry laboratory 2 sec 001, lab 208 cpb sec 002, lab 208 cpb sec 003, lab 208 cpb sec 004, lab 208 cpb.
The aldol condensation reaction - preparation of benzalacetophenones (chalcones) documents similar to ir ppt aldol condensation synthesis of trans p. Basic aldol cross-condensation wittig reaction synthesis of trans-p-anisalacetophenone from acetophenone and p-anisaldehyde under basic conditions in ethanol. Experiment 9: preparation of trans-p-anisalacetophenone (25 points) i summary in this experiment, you will be preparing trans-p-anisalacetophenone (mp 77-78°) from p-anisaldehyde and acetophenone via a crossed aldol condensation.
Che 175: mechanistic organic chemistry iii aldol addition and condensation lab 4 g/m 183 microscale synthesis of trans- p-anisalacetophenone. Introduction an , -unsaturated ketone can be prepared by conjugate addition of ethyl acetoacetate to trans-chalcone followed by an intermolecular aldol condensation reaction and dehydration a michael reaction is the nucleophilic addition of an , -unsaturated carbonyl compound the substituents on. Aldol condensation you are to prepare anisalacetophenone (aka 4-methoxychalcone) via an aldol condensation using the following protocol you will recrystallize the crude product from 95% ethanol.